Chemistry

 

Development of Electrochemical Capacitor Technology for DOD Applications

This project will establish a viable research program that will provide new capabilities and  broaden the university research base in support of national defense. The research will positively impact the development of supercapacitors, which are vital to the production of electrical vehicles and low-maintenance power sources for military applications. The research will take advantage of novel ceramic precursors to elaborate novel synthetic methods for the preparation of electrode materials that are currently under investigation for use in electrochemical capacitors. The research will also target the identification of new, superior electrode materials based on a combinatorial approach using water-based precursors. At the same time, the research will provide for the training of at least two graduate students, two undergraduate students, and a postdoctoral fellow in areas relevant to national defense.

Sponsor: OSRHE

PI: Allen Apblett

 

Development of Electrochemical Capacitor Technology for DOD Applications

This project will establish a viable research program that will provide new capabilities and broaden the university research base in support of national defense. The research will positively impact the development of supercapacitors that are vital to the production of electrical vehicles and low-maintenance power sources for military applications. The research will take advantage of novel ceramic precursors to elaborate novel synthetic methods for the preparation of electrode materials, which are currently under investigation for use in electrochemical capacitors. The research will also target the identification of new, superior electrode materials based on a combinatorial approach using water-based precursors. At the same time, the research will provide for the training of at least two graduate students, two undergraduate students and a postdoctoral fellow in areas relevant to national defense.

Sponsor: AFOSR

PI: Allen Apblett

 

Development of Technology Addressing Power Generation and Storage Challenges

For the proposed research, an established, vertically integrated, interdisciplinary, multi-university team will address several concerns of NASA in the area of electricity generation and storage. One goal will be the development of technology for roll-to-roll processing of metal-selenide-based solar cells into flexible polymeric substrates. At the same time, the project will target improvements in electrical storage through research that will allow the incorporation of novel ion conducting materials such as nano and microporous ceramic membranes and biological ion-conducting channels into lithium polymer batteries leading to enhanced lithium ion conductivity and battery performance.

Sponsor: University of Oklahoma 

PI: Allen Apblett

 

Expanding Efforts in the Ultrapure Water Group to Address Resin Chemistry Issues – Phase 2

Phase two covered two directions.  Defining the impact of the hyposthesized fouling mechanism on ion exchange resin performance and fouling the resins by specific chemical/physical means.

Sponsor: Electric Power Research Institute

PI: Alan Apblett

 

NanoNet Seed Grant

In this research, a new method, called the sol-gello method, was used to synthesize nanoparticlate yttrium iron garnet, an important target for high density magnetic and magneto-eprical drives and for the investigation of magnetic phenomena on the nanometer scale.

Sponsor: EPSCoR

PI: Alan Apblett

 

Process for in-situ Incapacitation of Explosives

This research will develop two promising techniques for rapidly and safely neutralizing explosives under ambient conditions. One method will involve the reduction of explosive compounds to non-explosive compounds. The second process decomposes aromatic or cyclic explosives by reacting them with organic amines at moderate temperatures.

Sponsor: Memorial Institute for the Prevention of Terrorism

PI: Allen Apblett, Nicholas Materer

 

New Mono and Bicyclic Saturated Azaheterocycles with Anesthetic and Antiarryhthmic Activity

This is a two-year project to develop the chemistry of judiciously selected heterocyclic systems that exhibit useful anti-arrhythmic and anesthetic properties. Our research team from OSU will work with a team at the National Academy of Sciences in Almaty, Kazakhstan.  The chemistry involves synthesis of members of the family of 3, 7-dihetera-bicyclo[3.31] nanones.

Sponsors: US Civilian Research and Development Fund and Oklahoma State Regents for Higher Education

PI: K.D. Berlin

 

Tandem Reaction Strategies for Drug Synthesis

This research is directed toward the study of tandem reaction for the efficient synthesis of new heterocyclic drug candidates. The reaction sequences being studied are initiated by reduction of an aromatic nitro group that is captured in subsequent reactions to generate novel structures for drug testing. The focus of this study is to develop and optimize each new process, elucidate its mechanism and scope and to search for ways to generate product compounds with higher stereoselectivity.

Sponsor: Oklahoma Center for the Advancement of Science and Technology (OCAST)

PI: Richard A. Bunce

 

Physics and Chemistry of Hydrogen-Bonded Nanoparticles and their Interactions with Strong Absorbates

This program continues to be unique in its focus on the properties of icy nanoparticles at the molecular level. Of particular current interest is the comparative nature of the surfaces of  ice and methanol particles and their respective interactions with strong H-bonding absorbates to T<140 K. Methanol particles have been selected for a study complementary to that of ice. The results of these particle studies are pertinent to several active areas of science including: solvation processes/H-bond chemistry in chemical and biochemical systems; H-bond chemistry and physics of (charged) icy particles in the atmosphere; and clathrate hydrates in fuel science and in the life-cycle of comets.

Sponsor: National Science Foundation

PI: J. Paul Devlin

 

Spectroscopic and Simulation Studies of Structures and Mobilities of Icy Surfaces and Adsorbates: Physics and Chemistry of Molecular Nanoparticles

The primary objective of this research is to further characterize the surface of crystalline ice (and related solids), in terms of both structure and kinetic response to a variety of adsorbates.

Sponsor: National Science Foundation

PI: J. Paul Devlin

 

Bioavailability of Aromatic Hydrocarbons and Dynamics of Their Interactions with Natural Organic Matter: Linkin Molecular- and Microbial-Scale Interactions

The purpose of this project is to bridge the gap between microbial-scale and molecular-scale interactions in order to define and quantitatively characterize bioavailability in terms of nanoscale processes. A predicted, applicable outcome from this research is the development of an enzymatic assay and a whole-microbe assay that utilize enzymes and bioluminescent bacteria, respectively, for characterizing and quantifying different levels of bioavailability in complex environmental matrices. It is intended that these assays will eventually permit risk assessments and remediation interventions to be evaluated by contaminated bioavailability rather than total contaminant concentration.

Sponsor: University of Oklahoma

PI: Margaret Eastman

 

Capillary Electrophoretic Analysis of Nanoparticle Bioconjugates

The primary objective of this project will be to demonstrate the capabilities of capillary electrophoresis in several model systems relevant for biosensor and drug delivery research. Simultaneously, the information about the protein/nanoparticles ratio in the bioconjugates, which still remain largely unknown will be obtained.

Sponsor: National Science Foundation, EPSCoR

PI: Ziad El Rassi

 

Capillary Electrophoresis-Based Biosensor for Water Quality

This project is concerned with the development of a capillary electrophoresis (CE)-based biosensor for the detection of microorganisms in water via the selective detection of biomarker compounds indicative of a particular microorganism. The CE-based biosensor will consist of an affinity capture capillary that contains an immobilized carbohydrate, which will selectively bind microbial lectins or adhesions that are present on bacteria cell surfaces.

Sponsor: Center for Water Research

PI: Ziad El Rassi

 

Electrically Driven Microseparation Methods for Pesticides and Metabolites

The broad objective of this investigation entails an integrated approach to the development of high performance capillary electrphoresis (HPCE) and capillary elctrochromatography (CEC) methods for the rapid, sensitive and efficient separation of neutral and charged pesticides and their metabolites. This broad objective will be approached by performing systematic studies on the mechanisms of the electrophoretic migration and electrochromatographic partitioning of pesticides and metabolites in HPCE and CEC. Also, detection methods for the sensitive determination of these pollutants by laser-induced fluorescence (LIF) are proposed as a plausible route to the broad objective.

Sponsor: US Department of Agriculture

PI: Ziad El Rassi

 

Biophotonics: Collaborative Research: Photoactivated Coupling of Nanoparticle Multilayers and Nerve Cells

In this project, a multidisciplinary and multi-university research team is investigating the dynamics and mechanisms of the live/lifeless matter interaction in a model system consisting of a thin film composed of nanoparticles and cultured nerve cells. Specifically, the objectives of the project are the following, (1) Preparation and optimization of biocompatible nanoparticle multilayers that can be attached to nerve cells. (2) Registration and characterization of the photoinduced nerve cell membrane currents and potentials following optical excitation of the interface as function of nanoparticle and biological structures.

Sponsor:  National Science Foundation

PIs: Warren Ford, Nicholas Kotov

Department of Physics: James Wicksted

 

Composite Latexes of Dendrimers and Ploystyrene

The goals of this research are to synthesize polymer colloids 15-100nm in diameter that are more nearly monodisperse than any made before and to assemble the spherical particles into colloidal crystals. The new particles are expected to self-assemble into colloidal crystalline arrays having lattice dimensions smaller than those of any previous colloidal crystals. The new materials may serve as calibration standards for electron microscopy, as optical filters and switches, and as templates for the synthesis of photonic bandgap materials.

Sponsor: American Chemical Society

PI: Warren Ford

 

EPSCoR Research Infrastructure improvement Plan

Continuing its long-term strategy of building upon existing strengths Oklahoma invests in the emerging fields of nanotechnology and functional genomics to bring them to a nationally competitive level. Both fields are federal as well as state priorities. Two multidisciplinary, multi-campus research groups were formed by investigators at Oklahoma State University, University of Oklahoma, OU Health Sciences Center, University of Tulsa, Oklahoma Medical Research Foundation and the private sector. The participating institutions provided start-up costs and sustained commitments to new faculty positions throughout the state. Targeting of reference standards, utilizing the Mesonet system, investment in improved microscopy equipment, statewide scientific symposia, promotion of linkages between university researchers and small business, extensive education and human resource and outreach programs were some of the goals charted for these groups. This will facilitate efforts to develop major research centers and enhance private sector research and development in the state and improve the statewide educational infrastructure to provide highly qualified students and graduates for the state’s emerging high technology businesses.

Sponsor: National Science Foundation, EPSCoR

PI: Warren Ford

 

New Materials from Radical Chain Polymerizations

This research will create three new types of polymers and test their optical and mechanical properties for potential use in optical communication devices and in improve plastics. The new materials will be 1) composites of silica in clear acrylic polymer matrices, 2) polymers that incorporate C60 (the most common Buckminsterfullerene), and 3) nanoparticles one millionth of an inch in diameter that are single polymer chains.

Sponsor: National Science Foundation

PI: Warren Ford

 

Radical Routes to New Copolymeric Materials

Two new types of polymers will be synthesized and characterized. Copolymers formed by emulsion polymerization, which has been used for the manufacture of synthetic rubber latex and coatings for more than fifty years, may provide a low cost alternative to the block copolymers that are used now to stabilize polymer blends. Model polyampholytes will be synthesized to enable testing of current theory of their structures and properties in aqueous solutions.

Sponsor: National Science Foundation

PI: Warren Ford

 

Molecular Laboratory Experiments in Chemistry

This project addresses four perceived problems in instruction at the introductory level in Chemistry. 1) Curriculum materials that will support an inquiry oriented instructional strategy. 2) The difficulty students have linking macroscopic, microscopic and symbolic levels of understanding. 3) Computer based instructional materials that are simple, dynamic and interactive. 4) Identification and addressing of student’s misconceptions. Instructional materials implemented followed a macroscopic (sensory)/microscopic/symbolic inquiry-oriented laboratory based model. Specifically the development of eight Molecular Level Experiment (MoLE) simulations: Gas Laws, Gas Phase Equilibrium, Kinetics, Atomic Structure and Periodcity, Acid-Base Chemistry, Calorimetry, Electrochemistry and Molecular and Solid State Structure. Each MoLE includes a powerful, interactive, dynamic computer simulation and is accompanied by a guided and open-inquiry activity.

Sponsor: National Science Foundation

PI: John Gelder

 

3D Tissue Constructs by Sequential Layering for Ex-vivo Immune System

This joint project between Oklahoma State University, University of Texas Medical Branch, Nomadics, Inc., and NASA is aimed at the development of an ex-vivo analog of the immune system via directed differentiation of hematopioetic stem cells seed on a new type of rigid scaffolds tailored specifically for this purpose. They will be made from colloidal crystals and their inverted replicas surface-modified by means of the layer-by-layer assembly. The resulting layered coating will provide optimal conditions for successful hematopioetic cell differentiation into immune cell lineages, which will be demonstrated by different experimental techniques. The developed procedure will be transferred into the bioreactor environment and optimized for further development of the immune tissues and vaccine productions.

Sponsor: United States Army Office of Research

PIs: Nicholas Kotov; Neil Purdie

 

All Fiber Faraday Rotator from Nanostructured Hybrid Films

In order to combine the benefits offered by iron garnet materials and those of all-fiber devices a new approach to the design of the MO Faraday rotator will be studied. The new type of Faraday rotator will take advantage of interaction of the evanescent filed on the surface of specially prepared fiber with a thin hybrid film of YIG nanoparticles. The objectives of the project will permit addressing the development of the evanescent field MO devices, as well as expanding the range of applications of nanostructured materials to fiber optics.

Sponsor: Oklahoma Center for the Advancement of Science and Technology, Williams Telecommunications

PI: Nicholas Kotov

 

Corrosion Preventative Coatings

Coating systems comprising an inhibitor-doped layer-by-layer (LBL) assembly basecoat and a dense organically-modified silicate (Ormosil) topcoat were investigated as corrosion resistant coatings for 2024-T3 aluminum alloy. A combination of the two coating methods was found to produce a synergistic enhancement of corrosion resistance characteristics, as determined using electrochemical techniques. Incorporation of an active corrosion inhibitor into the LBL layer was found to significantly improve corrosion resistance properties.

Sponsor: Sciperio

PI: Nicholas Kotov

 

Implanted Nanoparticle-Based sensor for in vivo Optical Monitoring of Analytes

Fabrication and testing of a novel implantable polymer-based sensor which responds to changes in glucose concentration can be accurately monitored using the interferometric/OCT technique. Specifically, the use of thin film technology and recent development in design and manufacturing of nanoparticles and micro-optics to design and test a multi-layered polymer-based implant with enhanced optical contrast that would be engineered to change optical and morphological properties as functions of glucose concentration where the changes in the implant can be accurately quantified non-invasively by monitoring the changes in optical path length within the probe. This will enable advancement in the field of non-invasive/minimally invasive glucose sensing toward development of a practical, accurate, and reliable sensor.

Sponsor: University of Texas Medical Branch

PI: Nicholas Kotov

 

New Materials for Photonics

This project will study an integrated approach to the study and design of new optical and opteolectronic materials in the university environment.  The primary goals for this research are the development of structural characterization and diversification of nanoparticles modified by metal complexes and study of their photochemical and photophysical properties.

Sponsor: National Sciences Foundation

PI: Nicholas Kotov

 

Phase II: Layer-By-Layer Assembled Films for Light Emitting Diodes from Semiconductor Nanoparticles

Light emitting diodes, LEDs, from poly(phenylene vinylene) and CdSe/CdS nanoparticles will be made using a layer-by-layer assembly technique, LBL. This thin film deposition method affords preparation of pinhole free molecularly organized layers with superior structural, optical and electrical characteristics. The primary research effort of this project will be focused on the improvement of the electron transport layer. Optimization of the multiplayer architecture of the electron layer is expected to improve the longevity of the device by the acceleration of heat dissipation in the thin film. Application of the LBL to the deposition of electron transfer layer can improve performance of LED as an element of flat panel displays, simplify R&D-to-production transition and reduce the cost of the product.

Sponsor: Nomadics, Air Force Office of Scientific Research

PI: Nicholas Kotov

 

Widegap Semiconductor III-Nitride Research

This research is aimed at the development of UV-blue range photonic and electronic materials and devices. The focus is III-nitride structures for applications in UV photodetectors, UV-blue laser diodes and high temperature electronics. AlGaN- and InGaN-based materials with large alloy concentration will be grown as well as nitride microstructure arrays. The final goal is to fabricate the prototype photonic devices. Time-resolved lasing and femtosecond pump-probe experiments will be carried out for this goal and a theoretical model developed.

Sponsor: Air Force Office of Scientific Research

PI: Nicholas Kotov

 

Mechanisms of Thermal and Optically-Driven Deposition on Semiconductor Surfaces

This project will investigate the use of ultra-violet (UV) radiation sources to selectively deposit and remove materials from a semiconductor surface. The use of the UV radiation to drive chemical reactions that are localized on the surface of a material should result in both the efficient utilization of energy and the elimination of possible side reactions. The objective is to explore the mechanisms of thermal and optically-driven deposition on semiconductor surfaces, focusing on the aspects of deposition of carbon nitride and metal films from halide containing precursors on variously terminated single-crystal silicon surfaces under both ultra-high vacuum and high-pressure conditions.

Sponsor: Center for Energy Research

PI: Nicholas Materer

 

Science and Engineering Research Center (SERC) for Durable Miniaturized Systems

The goal of this project is to establish an infrastructure for a distributed Center of Excellence for “Durable Miniaturized Systems” in the mid-west. Durability is defined as the synergistic reliable response of sub-systems as a function of operating time of the system, and it will be addressed through 1) establishing design and diagnostic tools at nano and micro dimensions, 2) developing a knowledge base of the effects of substrate processing, integration and manufacturing parameters on durability, 3) understanding the role of surfaces and interfaces within multi domain/ multi-signal subsystems and systems, and 4) investigating techniques for system prototyping.

Sponsor: University of Arkansas, National Science Foundation

PI: Nicholas Materer

 

A Novel Molecular Template for the Discovery of New Anticancer Drugs

A new methodology for synthesis of anticancer drugs will be developed in the research. Large libraries of chiral, small organic molecules with a drug-related structure, will be prepared based on a template molecule that was generated by a novel rearrangement.  This rearrangement is initiated by enzymatic hydrolysis, and renders large-scale production of the rearranged product in quite simple and mild conditions starting from inexpensive sources. Therefore, this method will not only increase the efficiency of the production of a diverse set of derivatives, but also lower the cost compared to the existing methods in drug discovery. The derivatives synthesized in this method will be screened for inhibitors of human papillomaviruses, and p210bcrabl kinase, in order to observe the preliminary results on the inhibitory effects.

Sponsor: Elsa U. Pardee Foundation

PI: Satomi Niwayama

 

Ocular Proteomics of Rodent Retina

The goal of this project is to define all the proteins expressed in rodent retinas in order to provide vision researchers with information regarding the proteins actually expressed in retinal cells.

Sponsor: National Institute for Health, University of Oklahoma Health Sciences Center

PI: Satomi Niwayama

 

Assays for Unsaturated Lipids: A Diagnostic Tool for Early Detection of Serum Lipid Disorders

Serum lipid disorders are accountable in the processes that initiate several debilitating diseases such as heart disease, cancer, diabetes, and mental disorders. The availability of a lipids specific diagnostic assay, routinely performed during regularly scheduled physical examinations, would be an indispensable aid as an early detection marker that would allow for earlier intervention thereby saving lives and reducing health care costs. With this goal in mind, a routine clinical analysis procedure is being perfected in which the following serum lipids, free cholesterol, unsaturated cholesterol esters, triglycerides, polyunsaturated fatty acids (PUFA’s), and phospholipids are simultaneously determined in a straightforward, single step, non-enzymatic assay in which unsaturated chemical colored products are produced. Detection is done using a combination f of absorbance and emission spectroscopies. Full range spectral data for serum samples that are representative of the various lipid disorders and disease states are subjected to successive Principal Component Analysis and Clustering Analysis algorithms. The diagnostic capability of the combined statistical analysis procedures is presented in the form of 2-D and 3-D cluster diagrams where relative spatial locations have been shown to correlate with specific lipid disorders.

Sponsor: State of Oklahoma

PI: Neil Purdie

 

Modeling of the Metal Cutting Process

This project works on the molecular dynamics (MD) simulations of the machining process. Objectives of the project are to advance the understanding of the machining process in general and, in particular, nanometeric cutting; and to model the submicron diamond turning process of both non-ferrous and semiconducting materials at the atomistic level

Sponsor: National Science Foundation

PIs: Lionel Raff

College of Architecture, Engineering and Technology: Ranga Komanduri

 

Multiscale Modeling and simulation of Material Processing

This research will address some critical issues involved in multiscale, multiphenomena material modeling, theory and simulation. The primary goal is to develop scaling laws for multiscale simulations, using such material testing techniques as tension and indentation, from atomistic to continuum, via mesoplasticity to enable the design engineer to use these scaling laws as a CAS tool for various materials design and processing applications.

Sponsor: Air Force Office of Scientific Research

PI: Lionel Raff

 

Cytochrome B5: A Case Study in Molecular Recognition

A project to develop the methodology for the bacterial expression of 13C-heme enriched b5 by combining the now elucidated biosynthetic pathway of heme and the special properties built in our expression system of the mitochondrial cytochrome b5. Expression of the cytochrome b5 gene turns on the synthesis of heme, which is then incorporated, in the over-expressed polypeptide, thus avoiding toxic concentrations of free macrocycle in the bacterial cell. Isotopically enriched heme will be used to develop new NMR spectroscopic studies of important heme proteins such as hemoglobin, myoglobin, and cytochromes b. Other types of spectroscopy such as infrared, resonance Raman, EPR and Möbauer will also benefit from the availability of isotopically enriched heme. Furthermore, radioiostopically enriched heme can be used to study the metabolism of heme, the influence of heme metabolism in diseases such as jaundice and prophyria, and the influence of heavy metals such as Pb and Cd in the metabolism of heme.

Sponsor: National Institute of Health, Oklahoma Center of the Advancement of Science and Technology (OCAST)

PI: Mario Rivera

 

Biochemical and Biophysical Characterization of Cytochrome b5 from Outer Mitochondrial Membrane

Membrane-anchored, mammalian cytochromes b5 are located in the endoplasmic reticulum and the outer membranes of mitochondria. Although MC cytochromes b5 have been identified from a number of mammalian sources the only OM cyt b5 that have been positively identified to date originates from rat liver. A systematic study will be conducted in which residues in the OM protein are replaced with the corresponding residues in the bovine Mc isoform. These studies will be preformed with the expectation of decreasing the stability and kinetic barriers for hemin release of rat OM cyt b5. It is also important to establish whether the biophysical properties of rat OM cyt b5 are restricted to this protein or rather are common to mitochondrial cytochromes b5. If the latter is true it would be an indication that nature has tailored these proteins for specific activity in the outer mitochondrial membrane. This would set the stage for future investigations regarding the specific function of these intriguing, yet poorly understood proteins.

Sponsor: National Science Foundation

PI: Mario Rivera

 

Chemistry Alternative Certification Pilot

This pilot program includes a week-long workshop in chemistry for 20 alternative certification candidates. This workshop will be directed toward those individuals who have the appropriate subject area content but lack the professional education background. The workshop is laboratory-centered and will emphasize a constructive methodology called Hypothesis-Based Learning.

Sponsor: State Department of Education

PIs: Mark Rockley

Center for Science Literacy: Smith Holt

 

Star Schools: The New Millennium Oklahoma State University

This is a multi-departmental education project directed toward improving, via distance education, the science and mathematics preparation of in-service middle school science and mathematics teachers.

Sponsor: Department of Education

PIs: Smith Holt

Department of Physics: Bruce Ackerson

Arts & Sciences Extension: Robert Brown

Microbiology & Molecular Genetics: James Blankemeyer

Department of Mathematics: James Choike

Department of Chemistry: Mark Rockley

 

Accurate Theoretical Predictions of the Properties of Energetic Materials

This research involves a multi-university, comprehensive theoretical/computational research program to develop, validate, benchmark and apply methods and models that will provide predictive capabilities for energetic materials. The focus of the project will be on developing accurate methods for simulating physics and chemical processes in condensed phases. This project will also provide opportunities to educate a number of young scientists in research of high relevance to Department of Defense missions.

Sponsor: United States Army Research Office

PI: Donald L. Thompson

 

Theoretical Studies of Nitramine Crystals

The basic goal of this research is to develop accurate models that describe the crystalline states of nitramine and nitro compounds. The models are formulated so they account for the fundamental thermodynamics, spectroscopic and kinetic properties of the solid,  as well as the liquid and gaseous phases of these materials.

Sponsor: Army Research Office

PI: Donald L. Thompson

 

Theoretical Studies of the Sensitivity of Energetic Materials

The goal of this research is to develop accurate potential energy surfaces that describe the initial physical and chemical changes tin ionic solids and H-bonded molecular crystals when subjected to heating or shocking.

Sponsor: Air Force Office of Scientific Research

PI: Donald L. Thompson

 

Theoretical Chemical Dynamics Studies of the Decomposition of Cyclic Nitramines

The focus of this research is on the development of theoretical methods for studying rates processes in large polyatimic molecules, particularly cyclic nitramines. The goal is to develop a better understanding of the fundamental chemical dynamics of decomposition reactions.

Sponsor: Army Research Office

PI: Donald L. Thompson

 

Theoretical Studies of the Behavior of Nanoenergetic Materials

The goal of this research is to develop models and methods for studying the chemical reactions occurring on and in nanoparticles composed of metals and energetic molecules, with and without polymer coatings.

Sponsor: Army Research

PI: Donald L. Thompson

 

Theoretical Chemical Dynamics Studies of Elementary Combustion Reactions

The goal of this research is to develop methods and perform studies of the reactions of polyatomic radicals involved in hydrocarbon combustion.

Sponsor: Department of Energy

PI: Donald L. Thompson